1.

When carbon tetrachloride is treated with excess of Benzene in presence of AlCl_3, the productformed is.

Answer»

Only`(C_6H_5)_3 C Cl`
Only `(C_6H_5)_4` C
A MIXTURE of a and b
None of the two

Solution :Fourth chlorine atomof the `C Cl_4` cannot be replaced by phenyl group because the CARBOCATION required for the introduction of the fourth phenyl group is too stable to react with benzene .
`(C_6H_3)_3 C Cl overset(AlCl_3)to underset("Highly stable")((C_6H_5)_3 C^(oplus) AlCl_4^(Ɵ))`
Due to steric FACTOR 4th nucleo philic cannot attack atcarbon atom.


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