1.

When H_(2)S gas is passed through aqueous solution of CuCl_(2), HgCl_(2), BiCl_(3) and CoCl_(2) in the presence of excess of dilute HCl, it fails to precipitate

Answer»

`CuS`
`HgS`
`Bi_(2)S_(3)`
`COS`

SOLUTION :The `k_(sp)` of CoS is QUITE high. In acidic medium, `S^(2-)` ion concentration gets suppressed. The concentration of `Co^(2+)` and `S^(2-)` ions REMAIN less than the `k_(sp)` VALUE of the salt. Therefore, CoS is not precipitated.


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