When silver chloride is dissolved in a large excess of ammonia, practically all silver ion can be assumed to exist in form of a sigle ionic species [Ag_(x)[NH_(3))_(y)]^(x+). Computerthe values of x and y using the following two cells. (a) Ag|0.4 xx 10^(-3)M AgCl, 1M NH_(3)||40 xx 10^(-3), MAgCl, 1M NH_(3)|Ag E_(cell) = 0.1185 V at 298 K (b) Ag|3 xx 10^(-3)M AgCl, 1M NH_(3)||3.0 xx 10^(-3)M, AgCl, 0.001 M NH_(3)|Ag E_(cell) = 0.1263 V at 298 K.

When silver chloride is dissolved in a large excess of ammonia, practi

1.	When silver chloride is dissolved in a large excess of ammonia, practically all silver ion can be assumed to exist in form of a sigle ionic species [Ag_(x)[NH_(3))_(y)]^(x+). Computerthe values of x and y using the following two cells. (a) Ag\|0.4 xx 10^(-3)M AgCl, 1M NH_(3)\|\|40 xx 10^(-3), MAgCl, 1M NH_(3)\|Ag E_(cell) = 0.1185 V at 298 K (b) Ag\|3 xx 10^(-3)M AgCl, 1M NH_(3)\|\|3.0 xx 10^(-3)M, AgCl, 0.001 M NH_(3)\|Ag E_(cell) = 0.1263 V at 298 K.
Answer» ANSWER :`X = 1, y = 2 ;`