1.

When solid lead iodide is added to water, the equilibrium concentration of I^(-) becomes 2.6xx10^(-3)M. What is K_(sp) for PbI_(2) ?

Answer»

`2.2xx10^(-9)`
`8.8xx10^(-9)`
`1.8xx10^(-8)`
`3.5xx10^(-8)`

Solution :`PbI_(2)hArrPb^(2+)+2I^(-)`
Thus, `PB^(2+)` ion concentration is half of the `I^(-)` ion concentration
`[I^(-)]=2.6xx10^(-3)M:.[Pb^(2+)]=1.3xx10^(-3)M`
`K_(SP)=[Pb^(2+)][I^(-)]^(2)`
`=(1.3xx10^(-3)) (2.6xx10^(-3))^(2)=8.8xx10^(-9)`.


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