1.

Whenredox reaction occurswithin the reactant , in which one component acts as oxidising agent andother component acts as reducing agent, then it is named as intra-molecular redox reaction, which usually occur in thermaldecomposition of ionic compounds. Which of the following compounds does not give nitrogen gas on heating ?

Answer»

`NH_(4)NO_(2)`
`(NH_(4))_(2)SO_(4)`
`NH_(4)ClO_(4)`
`(NH_(4))_(2)Cr_(2)O_(7)`

Solution :(A)`NH_(4)NO_(2)overset(DELTA)rarrN_(2)+2H_(2)O`
(B)`(NH_(4))_(2)SO_(4)overset(Delta)rarrNH_(3)+H_(2)SO_(4)`
(C)`2NH_(4)ClO_(4)overset(Delta)rarrN_(2)+Cl_(2)+2O_(2)+4H_(2)O`
(D) `(NH_(4))_(2)Cr_(2)O_(7)overset(Delta)rarrN_(2)+Cr_(2)O_(3)+4H_(2)O`


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