1.

Which amongst the following is the strongest acid?

Answer»

`CHBr_(3)`
`CH(CN)_(3)`
`CHI_(3)`
`CHCl_(3)`

Solution :Of the GIVEN compounds `CH(CN)_(3)` is STRONGEST acid because its conjugate base is stabilised by resonance.

`CHBr_(3) and CHI_(3)` are less stable as their conjugate bases are stabilised by inductive effect of HALOGENS. Conjugate base of `CHCl_(3)` INVOLVES back bonding between 2p and 3p orbitals


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