1.

Which buffer solution has maximum pH?

Answer»

mixture which is 0.1 M in `CH_3 COOH and 0.1 Mis CH_3 COONa [pK_a (CH_3COOH )= 4.74`
mixture which is `0.2 M CH_3 COOH and 0.2 M is CH_3 COONa`
mixture which is `0.1 M ` in ` NH_4 Cl and 0.1 M `in `NH_4 OH [pK_a (NH_4^(+)) =9.26]`
all the solution have EQUAL pH which is `4.74`

Solution :( a ) ` pH =pKa +log ""(0.1)/(0.1)=4.74`
( B ) ` pH =pKa +log ""(0.2)/(0.2)=4.74`
( C ) ` pH =pKa +log ""(0.1)/(0.1)=9.26`


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