1.

Which chloride is leastreaclivewith the hydrolysis point of view?

Answer»

`CH_(3)Cl`
`CH_(3)CH_(2)Cl`
`(CH_(3))_(3)CCl`
`CH_(2)=CH-Cl`

Solution :`underset("Vinyl CHLORIDE")CH_(2)*CH*Cl`
The halogen ATOM in vinyl chloride is not reactive as in other alkyl HALIDES. The non-reactivity of chlorine atom is DUE to resonance stabilisation. The e.p. on Cl-atom can participate in delocalisation (Resonance) to give two canonical structure.


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