1.

Which is the correct order of hydration enthalpy of alkali metals?

Answer»

`Li^(+) gt Na^(+) gt K^(+) gt Rb^(+) gt Cs^(+)`
`Cs^(+) gt Rb^(+) gt K^(+) gt Na^(+) gt Li^(+)`
`Cs^(+) gt Rb^(+) gt K^(+) gt Li^(+) gt Na^(+)`
`Na^(+) gt Li^(+) gt K^(+) gt Rb^(+)gt Cs^(+) `

Solution :
The hydration enthalpy of alkali metal ions decreases with increase in their ionic sizes
`Li^(+) gt Na^(+) gt K^(+) gt Rb^(+) gt Cs^(+)`
The degree of hydration of `Li^(+)` is the HIGHEST, DUE to which LITHIUM salts are MAINLY hydrated, e.g. LiCl, `H_(2)O`


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