1.

Which of the carbonates given below is unstable in air and is kep in CO_(2) atmosphere to avoid decomposition .

Answer»

`BeCO_(3)`
`MgCO_(3)`
`CaCO_(3)`
`BaCO_(3)`

Solution :Due to least ELECTROPOSITIVE character or least basicity of `Be(OH)_(2), BeCO_(3)` is LESS stable and hence decompose to give BEO and `CO_(2)` . Since the decomposition reaction is reversible , therefore to increase the stability of `BeCO_(3)` or to reverse the above equilibrium , `BeCO_(3)` is kept in an atmosphere of `CO_(2)` .
`BeCO_(3) hArr BeO + CO_(2)`


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