1.

Which of the following alcohol will give a black precipitate of manganese dioxide with alkaline KMnO_(4) ?

Answer»

`CH_(3)CH_(2)OH`
`CH_(3)-underset(CH_(3))underset(|)(CH)-underset(CH_(3))underset(|)overset(OH)overset(|)(C)-CH_(3)`
`(CH_(3))_(3)C-OH`
All of the above

Solution :Out of the given three choices (A, B and C) B and C are `3^(@)` alcohols ANS as such not oxidised with mild oxidising agents like alkaline `KMnO_(4)`. In the reaction `KMnO_(4)` is itself reduced to `MnO_(2)` (black ppt.)


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