1.

Which of the following attain the linear structure :

Answer»

`BeCl_(2)`
`NCO^(+)`
`NO_(2)`
`CS_(2)`

Solution :(A,D)
`BeCl_(2) ` (Cl - Be - Cl) and `CS_(2)` (S = C= S) both are linear. `NCO^(+)` is NON- linear . However,` ("remember that" ""^(-)NCO (""^(-)N = C = O))` is linear because it is isoelectronic with `CO_(2)`. `NO_(2)` is ANGULAR with bond angle `132^(@)` and each O - N bond length of 1.20 Å (intermediate between single and DOUBLE bond) .


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