1.

Which of the following complexes ionization isomerism ?

Answer»

`[Cr(NH_(3))_(6)]Cl_(3)`<BR>`[Cr(en)_(2)]Cl_(2)`
`[Cr(en)_(3)]Cl_(3)`
`[Co(NH_(3))_(5)Br]SO_(4)`

Solution :(1) No ANIONIC ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(2) No anionic ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(3) No anionic ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(4) `Br^(-) and SO_(4)^(-)` can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization ISOMERISM.


Discussion

No Comment Found