1.

Which of the following complexes ionization isomerism ?A. `[Cr(NH_(3))_(6)]Cl_(3)`B. `[Cr(en)_(2)]Cl_(2)`C. `[Cr(en)_(3)]Cl_(3)`D. `[Co(NH_(3))_(5)Br]SO_(4)`

Answer» Correct Answer - D
(1) No anionic ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(2) No anionic ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(3) No anionic ligand is present in coordination sphere for the exchange with `Cl^(-)` ion present in ionisation sphere.
(4) `Br^(-) and SO_(4)^(-)` can exchange their positions between coordination sphere and ionisation sphere. Hence it shows ionization isomerism.


Discussion

No Comment Found

Related InterviewSolutions