1.

Which of the following compound decolourises bromine water also reacts with PCl_(5) to give white fumes of HCl?

Answer»

`CH_(3)CH_(2)OH`
`CH_(3)-CH=CH-CH_(2)OH`
`CH_(3)OCH_(2)CH=CH_(2)`
both (B) and (C )

Solution :`H_(3)C-CH=CH_(2)-OH underset(("Red"))overset(Br_(2)//C Cl_(4))rarr H_(3)C-underset(("Colourless"))(underset(Br)underset(|)(CH)-underset(Br)underset(|)(CH))-CH_(2)-OH`
`H_(3)C-CH=CH-CH_(2)OH overset(PCl_(5))rarr HCl+POCl_(3)+H_(3)C-CH=CH-CH_(2)-CL`


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