1.

Which of the following compounds has the highest boiling point ?

Answer»

`CH_(3)CH_(2)CH_(2)Cl`
`CH_(3)CH_(2)CH_(2)CH_(2)Cl`
`CH_(3)CH(CH_(3))CH_(2)Cl`
`(CH_(3))C Cl`

SOLUTION :For isomeric halides, boiling POINT DECREASES with branching. So `CH_(3)CH_(2)CH_(2)CH_(2)Cl` has highest boiling point.


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