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Which of the following gases follows non-ideal behaviour?A. `N_(2)` gas having density `1.25g" L"^(-1)` at STPB. 2.8 g CO gas in 0.1 L flask exerting a pressure of 24.63 atm at 300 kC. 1.6 g `CH_(4)` in 0.5 L flask at 273 K exerting a pressure of 4 atmD. 0.1 g `H_(2)` gas at STP occupies volume of 1.12 L |
Answer» Correct Answer - C Non-ideal behaviour is followed if `pVnenRT` `p=(n)/(V)RT=(w)/(mV)RT=(dRT)/(m)` LHS,p=1 atm `RHS,(dRT)/(m)=(1.25g" L"^(_1)xx0.0821" L "atm " mol"^(-1)K^(_1)xx273K)/(28g" mol"^(-1)` Thus, `p=(dRT)/(m)=1` Thus, ideal behaviour `pV=nRT` `24.63xx0.1=(2.8)/(2.8)xx0.0821xx300 ` `2.463=2.463` Thus,ideal behaviour `pV=nRT` `4xx0.5=(1.6)/(16)xx0.0821xx273` 2=2.24 Thus,`pVnenRT` Thus, non-ideal behaviour `0.1 g H_(2)=0.05 " mol "H_(2)` `=0.05xx22.4L` at STP=1.12 L at STP Thus,ideal behaviour. |
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