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Which of the following graphs is correct for a zero order reaction? |
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Answer»
differential rate law :`(d[R])/(dt)=k` For zero order reaction Integrated rate law:`KT=[R]_(0)-[R]` `thereforeunderset(y)underset(uarr)[R]=underset(m)underset(uarr)-k underset(x)underset(uarr)t+underset(c)underset(uarr)([R]_(0))` This equation (i) is LIKE y=mx+c so ,`[R]tot` graph linear and the value of slope is NEGATIVE .This is option (D). `kt=[R]_(0)-[R]` `therefore-kt[R]-[R]_(0)` `therefore ([R]-[R]_(0))/(t)=-kt^(0)` `therefore` Rate `prop t^(0)` So rate `to` TIME graph is option (A). |
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