1.

Which of the following hydrocarbons is used for the major industrual synthesis of acetylene?

Answer»

`CH_4`
`C_2H_6`
`C_2H_4`
`CH_2`

Solution :`2CH_4overset(1500^@)toC_2H_2+3H_2`
The reaction proceeds (although it is highly endothermic) because there are twice as many moles of products (4 mol) as reactants (2 mol). This cause a significant increase in entropy and at this HIGH temperature, the `TDELTAS` term in the equation `DeltaG=DeltaH-TDeltaS` predominates, makin `DeltaG` negative even though `DeltaH` is positive.
The optimum time for this reaction is a mere 0.01s because if kept too long at this temperature `C_2H_2` (an endothermic compound) would decompose.


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