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Which of the following ions exhibits d-d transitions and paramagnetism as well?A. `CrO_(4)^(2-)`B. `Cr_(2)O_(7)^(2-)`C. `MnO_(4)^(-)`D. `MnO_(4)^(2-)` |
Answer» Correct Answer - D The no. of unpaired electrons in all the ions are listed. In `CrO_(4)^(2-),Cr^(+6)(n=0)` diamagnetic In `Cr_(2)O_(7)^(2-),Cr^(+6)(n=0)` diamagnetic In `MnO_(4)^(-),Mn^(+7)(n=0)` diamagnetic In `MnO_(4)^(2-),Mn^(+6)(n=1)` diamagnetic Thus `MnO_(4)^(2-)` ion is paramagnetic and also exhibits d-d transition. |
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