1.

Which of the following ions exhibits d-d transitions and paramagnetism as well?A. `CrO_(4)^(2-)`B. `Cr_(2)O_(7)^(2-)`C. `MnO_(4)^(-)`D. `MnO_(4)^(2-)`

Answer» Correct Answer - D
The no. of unpaired electrons in all the ions are listed.
In `CrO_(4)^(2-),Cr^(+6)(n=0)` diamagnetic
In `Cr_(2)O_(7)^(2-),Cr^(+6)(n=0)` diamagnetic
In `MnO_(4)^(-),Mn^(+7)(n=0)` diamagnetic
In `MnO_(4)^(2-),Mn^(+6)(n=1)` diamagnetic
Thus `MnO_(4)^(2-)` ion is paramagnetic and also exhibits d-d transition.


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