1.

Which of the following is the correct decreasing order of basicity of amines in gaseous phase?

Answer»

`(CH_(3))_(2)NH gt CH_(3)NH_(2) gt (CH_(3))_(3)N gt NH_(3)`
`(CH_(3))_(3)N gt (CH_(3))_(2)NH gt CH_(3)NH_(2) gt NH_(3)`
`(CH_(3))_(2)NH gt (CH_(3))_(3) N gt CH_(3)NH_(2) gt NH_(3)`
`(CH_(3))_(3)N gt CH_(3)NH_(2) gt (CH_(3))_(2)NH gt NH_(3)`

Solution :In the GASEOUS phase, BASICITY INCREASES as the +I-effect of the alkyl groups increases. THUS, option (b) is correct.


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