1.

Which of the following observations is correct andis used in the identification of carboxylic acids

Answer»

Carboxylic acids liberates `CO_(2)` gas from `NaHCO_(3)` SOLUTION
They produce FRUITY SMELL of esters when heated with alcohol in presence of conc. `H_(2)SO_(4)`.
Both (a) and (b)
Iodoform test

Solution :`RCOOH + NaHCO_(3) rarr RCOONa + H_(2)CO_(3) rarr CO_(2)`
(`RCOOD` more acidic than `H_(2)CO_(3)`)
Hence carboxlyic ACID liberates `CO_(2)` from solidum bicarbonate solution.
`RCOOH + R'OH overset("conc." H_(2)SO_(4))rarr underset((" Fruity smell"))underset(" Easter")(R-COOR' + H_(2)O)`
Hence they give fruity smell when warmedwith alcohol in the presence of conc. `H_(2)SO_(4)` Hence choice (c ) is CORRECT as (a) and (b) both are correct. Any carboxylic acid even `CH_(3)COOH` does not give iodoform test as the H-atom attached to C is not more acidic than H-atom attached to O. Hence (d) is incorrect.


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