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Which of the following observations is correct andis used in the identification of carboxylic acids |
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Answer» Carboxylic acids liberates `CO_(2)` gas from `NaHCO_(3)` SOLUTION (`RCOOD` more acidic than `H_(2)CO_(3)`) Hence carboxlyic ACID liberates `CO_(2)` from solidum bicarbonate solution. `RCOOH + R'OH overset("conc." H_(2)SO_(4))rarr underset((" Fruity smell"))underset(" Easter")(R-COOR' + H_(2)O)` Hence they give fruity smell when warmedwith alcohol in the presence of conc. `H_(2)SO_(4)` Hence choice (c ) is CORRECT as (a) and (b) both are correct. Any carboxylic acid even `CH_(3)COOH` does not give iodoform test as the H-atom attached to C is not more acidic than H-atom attached to O. Hence (d) is incorrect. |
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