1.

Which of the following pairs of ions is isoelectronic and isostructural ?

Answer»

`CO_(3)^(2-) , NO_(3)^(-)`
`CIO_(3)^(-) , CO_(3)^(2-)`
`SO_(3)^(2-), NO_(3)^(-)`
`CIO_(3)^(-), SO_(3)^(2-)`

Solution :In `CO_(3)^(2-)` , no. of electrons =` 6 + 3 xx 8 + 2 = 32 `
Shape = TRIGONAL planar
In `NO_(3)^(-)`, no . of electrons= ` 7 + 3 xx 8 + 1= 32`
Shape = trigonal planer
In `SO_(3)^(2-) `, no of electrons = ` 16 + 3 xx 8 + 2 = 42 `
Shape = pyramidal
In `CIO_(3)^(-)`, no. of electrons ` 17 + 3 xx 8 + 1= 42`
Shape = pyramidal


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