InterviewSolution
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InterviewSolution
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Which of the following reactions occurs wiyh reacemization?A. `CH_(3)CH_(2)CHH(OH)CH_(2)Br+OH^(-)rarrCH_(3)CH_(2)CH(OH)CH_(2)OH+Br^(-)`B. `CH_(3)CH_(2)CH=CH =CH_(2)+D_(2)overset(catalyst)rarrCH_(3)CH_(2)CH(D)CH_(2)D`C. `CH_(3)CH_(2)CH(OH)CH(CH_(3))_(2)+CH_(3)COCIrarrCH_(3)CH_(2)CH(OCOCH_(3))CH(CH_(3))_(2)+HCI`D. `CH_(3)CH(NH_(2))COOH+NaOHrarrCH_(3)CH_(2)(NH_(2))COO^(-)Na^(+)+H_(2)O` |
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Answer» Correct Answer - B The product has a chiral center `(D` being sufficiently different from `H)`, both enantiomers are formed in equal amounts because `D_(2)` adds to the enantiotopic faces of the alkene equally. Reactions `(1),(3)` and `(4)` occur with retention because no bond-breacking occurs at the chiral carbon. To answers this, we need to draw out the structurnes of the reactants and the products and identify and chiral centers. |
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