1.

Which of the following species has lowest first ionization potential ?

Answer»

O
`O_(2)`
`O_(2)^(+)`
`O_(2)^(-)`

Solution :In O-atom , the ELECTRON is to be removed from 2p
while in `O_(2) , O_(2)^(+) and O_(2)^(-)` , electron is to be
removed from`pi^(**) (2p_(x)) or pi^(**) (2p_(y))` which has
higher ENERGY and hence less stable . Further , `O_(2)^(-)`
is least stable DUE to GREATER number of ELECTRONS
in the antibonding molecularorbitals .


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