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Which of the following statement is/are false ?A. `Delta_rS` for `1/2Cl_2(g)toCl(g)` is positiveB. `DeltaElt0` for combustion of `CH_4(g)` in a sealed container with rigid adiabatic systemC. `DeltaG` is always zero for a reversible process in a closed systemD. `DeltaG^@` for an ideal gas reaction is a function of pressure |
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Answer» Correct Answer - BCD `(A)Cl_(2_(g))to2Cl_((g)) " " ` randomness is increasing (B) In closed container `DeltaV=0` hence work cone is zero. There is no heat exchange . Hence `DeltaE=q+W=0` ( C)`DeltaG` will be zero only when equilibrium is reached. `:.` not a function of pressure (D)`DeltaG^@= - RT` In `K_(eq)` `:.` not a function of pressure |
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