1.

Which of the following statements are correct ? (a) All the three N___O bond lengths in `HNO_(3)` are equal. (b) All P___Cl bond lengths in `PCl_(5)` molecule in gaseous state are equal (c ) `P_(4)` molecule in white phosphrus have angular strain therefore white phosphorus is very reactive (d) `PCl_(5)` is ionic in solid state in which cation is tetrahedral and anion is octahedral . And anion is octahedral.

Answer» Correct Answer - C::D
(a) All the three N__O bond lengths in `HNO_(3)` are not equal.
(b) All P___Cl bond lengths in `PCl_(5)` molecule in gaseous state are not equal. Axial bond is longer than equatorial bond.
(c ) `P_(4)` molecule in white phosphorous have angular strain therefore white phosporous is very reactive.
(d) `PCl_(5)` is ionic in soild state in which cation is tetrahedral and anion is octahedral.
Cation - `[PCl_(4)]^(+)`
Anion - `[PCl_(6)]^(-)`


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