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Which of the following statements is/are correct, when a mixture of `NaCl` and `K_2Cr_2O_7` is gently warmed with concentrated `H_2SO_4`?A. Deep red vapours are evolved.B. The vapours when passed into NaOH solution give a yellow solution of `Na_2CrO_4`.C. Chlorine gas is evloved.D. Chromyl chloride is formed. |
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Answer» Correct Answer - A::B::D `K_2Cr_2O_7+6H_2SO_4+4NaClto2KHSO_4+4NaHSO_4+2CrO_2Cl_2+3H_2O` Orange-red vapours of `CrO_2Cl_2` are produced. When these vapours are passed through `NaOH`, a yellow solution of `Na_2CrO_4` is produced. `CrO_2Cl_2+4NaOHtoNa_2CrO_4+2H_2O+2NaCl` |
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