1.

Which of the following statements is/are incorrect ?

Answer»

Nitrobenzene will give meta-nitrotoluene on reaction with `CH_3Cl//AlCl_3`
Chlorobenzene will give meta-substituted product on electrophilic substitution SINCE it EXERTS -I gt + M effect.
n-Propyl benzene can be easily obtained on Friedral CRAFTS alkylation of benzene with n-propyl chloride.
Toluene can be obtained in better yield when excess of benzene withreact with `CH_3Cl//AlCl_3`.

Solution :(A)In highly de-activated ring Friedal Crafts reaction is not possible.
(B)Chloro group is ortho-para director.
(C )In Friedal Craft reaction the electrophile carbocation rearranges.
(D)To AVOID polyalkylation aromatic substrate is taken in excess.


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