1.

Which of the following will dissolve in aqueous Na_(2)CO_(3) ?

Answer»

PHENOL
2,4,6-Trimethylphenol
2,4,6-Trinitrophenol
2,4-Dinitrophenol

Solution :Phenol is less ACIDIC than `H_(2)CO_(3)`. As such phenol does not dissolve in aqueous `Na_(2)CO_(3)`. However, PRESENCE of electron WITHDRAWING group `(-NO_(2))` makes it more acidic. Thus 2, 4-dinitrophenol and 2,4,6-trinitrophenol are more acidic than `H_(2)CO_(3)` and as such dissolve in `Na_(2)CO_(3)` to diaplce weaker acid `H_(2)CO_(3)`.


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