1.

Which of the following will produce the highest risein temperature?

Answer»

67 mL of 1M NaOH `+`33 mL of 0.5M `H_(2)SO_(4)`
33 mL of 1 M NaOH `+`67 mLof 0.5M `H_(2)SO_(4)`
40 mL of 1 M NaOH`+` 60 mL of 0.5 M `H_(2) SO_(4)`
50 mL of 1 M NaOH `+` 50 mLof 0.5M `H_(2)SO_(4)`

Solution :0.5M `H_(2)SO_(4) -= 1NH_(2)SO_(4)`. HENCE,completeneutralization will TAKE placeonly in (d) where 50 mL OF1 MNaOH `(= 1N NaOH)` willneutralize 50 mLof0.5 M`H_(2)SO_(4)(1 N H_(2)SO_(4))`. Thus HEAT evolved will be maximum and so rise in temperature will be highest.


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