1.

Which of the two structures (A) and (B) given below is more stabilised by resonance. Explain (A) CH_(3)COOH (B) CH_(3)COO^(-)

Answer»

Solution :(B) `CH_(3)COO^(-)` is more stabilised
(A) Resonance structure of `CH_(3)COOH`:

The separation of charge is in structure (II) so, it is more ENERGY containing and less stable.
`THEREFORE` There is a less stabilisation of structure (A).
(B) Resonance structure of `CH_(3)COO^(-)`:

Both the resonance structure of compound (B). i.e. x and y are of eqal energy and hence contribute equally towards the resonance hybrid of structure (B) is more stable than structure (A).


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