1.

Which one of the following arrangements does not give the correct picture of the trends indicated against it ? (i) F_(2) gt Cl_(2) gt Br_(2) gt l_(2) : Oxidizing power (ii) F_(2) gt Cl_(2) gt Br_(2) gt l_(2) : Electron gain enthalpy (iii) F_(2) gt Cl_(2) gt Br_(2) gt l_(2) : Bond dissociation energy (iv) F_(2) gt Cl_(2) gt Br_(2) gt l_(2) : Electronegativity.

Answer»

II and iv
I and iii
ii and iii
ii, iii and iv

Solution :From the given options we find option (i) is correct. The oxidising POWER of halogens follow the order `F_(2) gt Cl_(2) gt Br_(2) gt I_(2)`. Option (ii) is incorrect because it in not the correct order of electron gain enthalpy of halogens.
The correct order is `Cl_(2) gt F_(2) gt Br_(2) gt I_(2)` . The low value of `F_(2)` than `Cl_(2)` is DUE to its small size.
Option (iii) is incorrect. The correct order of bond dissociation energies of halogens is
`Cl_(2) gt Br_(2) gt F_(2) gt I_(2)`
Option (iv) is correct. It is the correct order of ELECTRONEGATIVITY VALUES of halogens. Thus option (ii) and (iii) are incorrect.


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