1.

Which one of the following arrangements does not give the correct picture of the trends indicated against it? (a) F2 > Cl2 > Br2 > I2 : Bond dissociation energy (b) F2 > Cl2 > Br2 > I2 : Electronegativity (c) F2 > Cl2 > Br2 > I2 : Oxidizing power (d) F2 > Cl2 > Br2 > I2 : Eiectron gain enthalpy

Answer»

The correct option is : (a) F2 > Cl2 > Br2 > I2 : Bond dissociation energy 

(d) F2 > Cl2 > Br2 > I2 : Eiectron gain enthalpy

Explanation:

In case of diatomic molecules (X2) of halogens the bond dissociation energy decreases in the order :

Cl2 > Br2 > F2 > I2 

The oxidising power, electronegativity and reactivity decrease in the order :

F2 > Cl2 > Br2 > I2 

Electron gain enthalpy of halogens follows the given order:

Cl2 > F2 > Br2 > I2 

The low value of electron gain enthalpy (electron enthalpy) of fluorine is probably due to small size of fluorine atom.



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