1.

Which one of the following represents the correct order of increasing first ionization enthalpy of Ca, Ba, S, Se and Ar ?

Answer»

`Ca ltSlt Ba lt Ase lt Ar`
`S lt Se lt Ca lt Ba lt Ar`
`Ba lt Ca lt Se lt S lt Ar`
`Ca lt Ba lt S lt Se lt Ar`

Solution :`Ba lt Ca lt Se lt S lt Ar`
`{:("Period"3^(rd),16^(S),18^(Ar)),("Period"4^(TH),20^(Ca),34^(Se)),("Period"6^(th),56^(Ba),):}`
First ionization potentials increases in a period with increasing of atomic number
`:.{:((i)Delta_(i)H(Ar)gt Delta_(i)H_(i)(S)),((ii)Delta_(i)H(Se)gt Delta_(i)H(Ca)):}}....(x) `
And in a group first ionization enthalpy DECREASES from top to BOTTOM
`:.{:((i)Delta_(i)H(Ba)lt Delta_(i)H(Ca)),((ii)Delta_(i)H(Se)lt Delta_(i)H(S)):}}....(y) `
From (x)and (y) we can SAY that order of first ionization potential is as
`Ba lt Ca lt Se lt S lt Ar`


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