1.

Which one of the following undergoes nitration most readily ?

Answer»

Acetophenone
Benzonitrile
Benzaldehyde
benzene

Solution :Acetophenone, benzonitrile, benzaldehyde and benzoic acid all contain ELECTRON-withdrawing GROUPS, therefore, in all these compounds the electron density over the phenyl ring is LOWER than in benzene. Thus, benzene UNDERGOES electrophilic nitration most READILY.


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