1.

Which product is formed on chlorination of (CH_(3))_(3)CH ? Also give comparison of their composition.

Answer»

SOLUTION :`overset(1^(@))(C)H_(3)-underset(""^(1^(@))(CH_(3)))underset(|)overset(1^(@))(CH)-overset(1^(@))(CH_(3))underset(hv)overset(Cl_(2))rarrunderset((A))underset(3^(@)"butylchloride")(CH_(3)-underset(CH_(3))underset(|)overset(Cl)overset(|)(C)-CH_(3))+underset((B))underset(1^(@)-"chloride")underset(CH_(3))underset(|)(CH)-CH_(2)Cl`
A and B both are obtained from the monochloroalkane, (A) proportion `gt` product (B) proportion. Because compound (A) formed which DEPEND on production RATE of `3^(@)` hydrogen `gt` (B) formed which depends on `1^(@)` hydrogen atoms.


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