1.

Which resonance form in each of the following sets is the major contributor to the real structure? (i) underset((A))(CH_(2)-underset(CH_(3))underset(|)(C)-CH)=CH_(2)harrunderset((B))(overset(+)(CH_(2))-underset(CH_(3))underset(|)(C)=CH)-overset(-)(CH_(2)) harr underset((C))(overset(-)(CH_(2))-underset(CH_(3))underset(|)(C)=CH)-overset(+)CH_(2) (ii) underset((A))(CH_(3)-overset(O)overset(||)(C)-CH)=CH_(2)harrunderset((B))(CH_(3)-overset(O^(-))overset(|)underset(+)(C)-CH)=CH_(2)harr underset((C))(CH_(3)-overset(O^(-))overset(|)(C)=CH)-overset(+)(CH_(2)) (iii) underset((A))(CH_(2)=CH-CH=CH_(2))harrunderset((B))(overset(+)(C)H_(2)-CH=CH)-overset(-)CH_(2)harrunderset((C))(overset(-)(CH_(2))-CH=CH-overset(+)(CH_(2))

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Answer :FORM A in (i), (ii), (iii) and form C in (IV) is the major contributor because in these STRUCTURES each atom has OCTET and no formal charge is present.


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