1.

Whichof the followingthe ratioof the sizesofcationof anionis smallest ?

Answer»

`NACI`
`KCI`
`MgC1_(2)`
`CaF_(2)`

Solution :Onmovingdown agroupionicradiusincreases .
Thus`Na^(+)` has smallerradiusthan `K^(+)` and `Mg^(2+)` has smallerradiusthan `CA^(2+)`.
Incontraston movingacrossa period , ionicradiusdecreases .Thus`Mg^(2+)` has smallerradiusthan`Ca^(2+)` .In other words `Mg^(2+)` has thesmallestradiusamongst `Na^(+) , K^(+) , Mg^(2+) ` and `Ca^(2+)`
Amongst halogens `C1^(-)` has lergestradiusthan`F^(-)`. thus`MgC1_(2)` has thesmallestratioof the sizeof cationto anion.


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