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Whichof the followingwill havethe mostnegativeelectrongainenthalpyand whichthe leastnegative? P, S, Cl, F Explainyouranswer.

Answer»

Solution :Arrangingthe givenatomsintodifferent groupsandperiodsin orderof increasingatomicnumbers

Aswe moreacrossa periodfromleftto rightthe electrongain enthalpybecomesmore andmorenegative while withthe groupfrom top tobottom it BECOMES lessand less NEGATIVE. Therefore , Fshouldhave themostnegativeelectrongainenthalpywhile Pshouldhave theleastnegativeelectron gain enthalpy. Butaddingan electron to LARGER 3P- orbitall of CI.HenceCl has themostnegativeelectron gainenthalpywhile PHAS thelest negativeelectron gainenthalpy .


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