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Why `E^(@)` value of Mn, Ni and Zn are more negative than expected ?

Answer» The statement alos implies that why these transition metal are stronger reducing agents than expected. This is related to the stabilities of the divalent cations which are formed by the loss of electrons. The extr- stabilities of `Mn^(2+)` and `Zn^(2+)` ions is due to the presence of five half filled `(3d^(5))` and fully filled orbitals `(3d^(10))`. However, the extra stability of `Ni^(2+)` ion is because of its high negative enthalpy of hydration because of the small ionic size.


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