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Why `E^(@)` values for Mn, Ni and Zn are more negative than expected ?

Answer» The values of `E^(@)` for Mn and Zn are more negative than expected because `Mn^(2+)` and `Zn^(2+)` have stable exactly half- filled and fully filled configuration respectively. The high negative value of `E^(@)` for Ni is due to its highest negative enthalpy of hydration


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