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Why is diamond a had conductor of electricity but a good conductor of heat ?

Answer» Conduction of electricity of essentially requires movement of electrons while conduction of heat does not necessarily require movement of electrons. Since in diamond, all the electrons are firmly held C-C, `sigma`-bonds, there are no free electrons in a diamond crystal. Therefore, diamond is a bad conductor of electricity.
In contrast, conduction of heat is due to thermal vibrations from one atom to the other which is easier in a compact crystal of diamond.


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