1.

Write IUPAC names of the products obtained by addition reactions of HBr to hex-1-ene (i)in presence of peroxide and (ii)in the absence of peroxide.

Answer»

Solution :(i)In PRESENCE of peroxides, anti-Markovnikov's addition occurs and 1-bromohexane is FORMED . <BR> `underset"Hex-1-ene"(CH_2=CH-CH_2-CH_2-CH_2-CH_3+HBr ) underset"(Anti-Mark. addn.)"OVERSET"PEROXIDE"to underset"1-Bromohexane"(undersetunderset(Br)|CH_2-CH_2-CH_2-CH_2-CH_2-CH_3)`
(ii)In absence of peroxides, Markovnikov's addition occurs and 2-bromohexane is formed .
`underset"Hex-1-ene"(CH_2=CH-CH_2-CH_2-CH_2-CH_3+HBr ) underset"(Mark. addn.)"overset"No peroxide"to underset"2-Bromohexane"(CH_3-undersetunderset(Br)|CH-CH_2-CH_2-CH_2-CH_3)`


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