1.

Write mathematical equations of first law of thermodynamics for the following processes:a. Adiabatic process b. Isochoric process

Answer»

a. Adiabatic process: The mathematical expression of first law of thermodynamics is 

ΔU = q + W. 

In adiabatic process, q = 0. 

Hence, the mathematical expression of first law of thermodynamics for adiabatic process is, 

ΔU = 0 + W 

∴ ΔU = +W 

or - ΔU = - W

b. Isochoric process: The mathematical expression of first law of thermodynamics is

ΔU = q + W (W = - pex ΔV). 

In isochoric process, ΔV = 0, W = 0 

Hence, the mathematical expression of first law of thermodynamics for isochoric process is, 

ΔU = qv + 0 

∴ ΔU = qv



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