Write the disproportionation reactions of the following species : (i) ClO^(-) (ii) ClO_3^(-) (iii) Cl^(-) (iv) ClO_3^(-) (v) ClO_4^(-) (vi) Tl^+

Write the disproportionation reactions of the following species : (i)

1.	Write the disproportionation reactions of the following species : (i) ClO^(-) (ii) ClO_3^(-) (iii) Cl^(-) (iv) ClO_3^(-) (v) ClO_4^(-) (vi) Tl^+
Answer» Solution :(i) `OVERSET(+1)(3Cl)O^(-)rarroverset(-1)(2C)l^(-)+overset(+5)(ClO_3^(-))` (ii) `overset(+5)(4ClO_3^(-))rarroverset(-1)(Cl^-)+overset(+5)(2ClO_3^(-))` (iii) `Cl^-` does not DISPROPORTIONATE. (iv) `overset(+3)(ClO_2^-)rarroverset(-1)(Cl)+overset(+5)(2ClO_3^(-))` (v) `ClO_4^(-)` does not disproportionate because in this oxoanion , chlorine is present in its highest oxidation state i.e., +7. (iv) `3Tl^(+)hArroverset(0)(2Tl)+Tl^(3+)`