1.

Write the IUPAC name of the complex `[Cr(NH_(3))_(4)Cl_(2)]^(+)` . What type of isomerism does it exhibit ?

Answer» The IUPAC name of the complex `[Cr(NH_(3))_(4)Cl_(2)]^(+) `is
Tetraamminedichloridochromium (III) ion.
This complex exhibits geometrical isomerism. `[Cr(NH_(3))_(4)Cl_(2)]^(+) is a [MA_(4)B_(2)]` type of complex, in which the two chloride ligands may be oridented cis ans trans to each other.
See also Q. 23, Set - III, Outside Delhi - 2012.


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