1.

Write the name, stereochemistry and magnetic behaviour of the following:(At. nos. Mn = 25, Co = 27, Ni = 28)(i) K4[Mn(CN)6](ii) [Co(NH3)5Cl]Cl2(iii) K2[Ni(CN)4]​

Answer»
Name of the ComplexHybridisation of metal ion involvedGeometry of complexMagnetic behaviour
Potassium hexacyano manganate (II)

 
d2sp3Octahedral

 
Paramagnetic



 
Pentaammine Chloridocobalt (III) Chloride

 
d2sp3Octahedral

 
Diamagnetic


 
Potassium tetra cyanonikelate (II)

 
dsp2Square planar

 
Diamagnetic

 



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