Saved Bookmarks
| 1. |
Write the name, the structure and the magnetic behaviour of each one of the following complexes : (i) [Pt(NH_(3))_(2)Cl(NO_(2))] (ii) [Co(NH_(3))_(4)Cl_(2)]Cl (iii) Ni(CO)_(4)""(Al nos, Co = 27 , Ni = 28, Pt = 78) |
|
Answer» SOLUTION :(i) `[Pt(NH_(3))Cl(NO_(2))]` IUPACname : Diammine chloridenitrito - N- platinum (ii) Structure : Square planar `(dsp)^(2)` MAGNETICBEHAVIOUR : Diamagnetic (ii) `[Co(NH_(3))_(4)Cl_(2)]Cl` Tetraamine dichlorido cobalt (III) Chloride Hybriisation : `d^(2) sp^(3)` Shape : octahedral Magnetic property : diamagnetic .  (iii) `[Ni(CO_(4))]` Tetracarbonylnickel `(O)` Behaviour: diamagnetic . Structure = Tetrahedral The complexes in which formed by hybridisation of one S and three p-orbita to obtain FOUR equivalent orbital ORIENTED tetrahedrally. 
|
|