1.

You observe that carbon dioxide sublimes. Which of the following statements about the signs of this process is/are true? (I) Work (w) is positive. (II) Heat (q) is negative. (III) Change in Gibbs free energy (∆G) is positive. (IV) Change in entropy (∆S) is positive. 1. II and III 2. I only 3. I and II 4. I, II and III 5. IV only 6. III and IV

Answer»

Correct option 5. IV only

Explanation:

Sublimation results in a significant increase in the volume of the system, allowing it to do work on its surroundings, i.e. the pressure-volume work function is negative. Sublimation is also an endothermic process, making heat positive. Since the process described ”happens” as a given in the problem, the change in free energy must be negative. Change in entropy must be positive since a solid is becoming a gas.



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